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Mainly the # of PCI slots difference
If you need the extra PCI slots (i.e. you have wireless adapter, aftermarket sound card, tv tuner, etc etc) then you should go with an ATX board that has all the slot you need, otherwise, i would just go with mAtx so you have the option of using both mAtx and Atx case.
Btw, I "THINK" most enthusiasts mb that are good for ocing are ATX.
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