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If it's just 10k, I'd carb load a few days before the run and then take it easy a day or two before for pre-run fueling.
I remember riding 17km from home to the run, ran, then 17km ride back home on a single gear and did no special loading. Still ended up ok with a 51min finish, my arms were more sore than anywhere else actually.
Oh, i'd stay away from caffeine if i were you. The run itself will get blood pumping through your system rather quick. It's good that they start going downhill on georgia first for a warm up. the first 2 km are easy, just watch going up hornby and the burrard bridge that's a bit strenuous. Other than that, the run is pretty flat.
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